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1: J Am Chem Soc. 2008 Feb 6;130(5):1574-5. Epub 2008 Jan 11.
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Formation and stability of a vinyl carbanion at the active site of orotidine 5'-monophosphate decarboxylase: pKa of the C-6 proton of enzyme-bound UMP.

Amyes TL, Wood BM, Chan K, Gerlt JA, Richard JP.

Department of Chemistry, University at Buffalo, Buffalo, New York 14260, USA.

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PMID: 18186641 [PubMed - indexed for MEDLINE]