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Wolfgang Buckel
Laboratorium für Mikrobiologie, Philipps-Universitat Marburg, D-35032 Marburg, Germany

Faculty Member: Chemical Biology > Biocatalysis [ since 4 July 2001 ]
[ Evaluations ]
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Evaluations

Identification and characterization of Escherichia coli thioesterase III that functions in fatty acid beta-oxidation.
Nie L, Ren Y, Schulz H
Biochemistry 2008 Jul 22 47(29):7744-51 [abstract on PubMed] [related articles] [full text] [order article]
Selected by | Wolfgang Buckel
Evaluated 28 Jul 2008

A dicarboxylate/4-hydroxybutyrate autotrophic carbon assimilation cycle in the hyperthermophilic Archaeum Ignicoccus hospitalis.
Huber H, Gallenberger M, …, Eisenreich W, Fuchs G
Proc Natl Acad Sci U S A 2008 Jun 3 105(22):7851-6 [abstract on PubMed] [related articles] [full text] [order article]
Selected by | Wolfgang Buckel
Evaluated 17 Jun 2008

Aromatizing cyclohexa-1,5-diene-1-carbonyl-coenzyme a oxidase: characterization and its role in anaerobic aromatic metabolism.
Thiele B, Rieder O, …, Müller M, Boll M
J Biol Chem 2008 May 27 [abstract on PubMed] [related articles] [FREE full text]
Selected by | Wolfgang Buckel with none
Evaluated 10 Jun 2008

Characterisation of an acyl-CoA : carboxylate CoA-transferase from Aspergillus nidulans involved in propionyl-CoA detoxification.
Fleck CB, Brock M
Mol Microbiol 2008 Mar 4 [abstract on PubMed] [related articles] [full text]
Selected by | Wolfgang Buckel
Evaluated 26 Mar 2008

Evidence for the Involvement of Acid/Base Chemistry in the Reaction Catalyzed by the Type II Isopentenyl Diphosphate/Dimethylallyl Diphosphate Isomerase from Staphylococcus aureus.
Thibodeaux CJ, Mansoorabadi SO, …, Chang WC, Liu HW
Biochemistry 2008 Jan 30 0 [abstract on PubMed] [related articles] [full text]
Selected by | Wolfgang Buckel
Evaluated 5 Feb 2008

Re-investigation of the catalytic mechanism of formyl-CoA transferase, a class III CoA-transferase.
Berthold CL, Toyota CG, Richards NG, Lindqvist Y
J Biol Chem 2007 Dec 27 [abstract on PubMed] [related articles] [FREE full text]
Selected by | Wolfgang Buckel
Evaluated 15 Jan 2008

Thiamine biosynthesis in Escherichia coli: identification of the intermediate and by-product derived from tyrosine.
Kriek M, Martins F, …, Croft A, Roach PL
Angew Chem Int Ed Engl 2007 46(48):9223-6 [abstract on PubMed] [related articles] [full text] [order article]
Selected by | Wolfgang Buckel
Evaluated 28 Nov 2007

The Effect of a Glu370Asp Mutation in Glutaryl-CoA Dehydrogenase on Proton Transfer to the Dienolate Intermediate(,).
Rao KS, Fu Z, …, Kim JJ, Frerman FE
Biochemistry 2007 Dec 18 46(50):14468-77 [abstract on PubMed] [related articles] [full text] [order article]
Selected by | Wolfgang Buckel
Evaluated 28 Nov 2007

Cyclohexane carboxylate and benzoate formation from crotonate in Syntrophus aciditrophicus.
Mouttaki H, Nanny MA, McInerney MJ
Appl Environ Microbiol 2007 Feb 73(3):930-8 [abstract on PubMed] [related articles] [FREE full text]
Selected by | Wolfgang Buckel
Evaluated 24 Aug 2007

Kinetics and mechanism of oxygen-independent hydrocarbon hydroxylation by ethylbenzene dehydrogenase.
Szaleniec M, Hagel C, …, Witko M, Heider J
Biochemistry 2007 Jun 26 46(25):7637-46 [abstract on PubMed] [related articles] [full text] [order article]
Selected by | Wolfgang Buckel
Evaluated 29 Jun 2007

A manganese(IV)/iron(III) cofactor in Chlamydia trachomatis ribonucleotide reductase.
Jiang W, Yun D, …, Krebs C, Bollinger JM
Science 2007 May 25 316(5828):1188-91 [abstract on PubMed] [related articles] [full text] [order article]
Selected by | Amy Rosenzweig / Angela Wilks / Wolfgang Buckel
Evaluated 15 Jun 2007

The crystal structure of yeast fatty acid synthase, a cellular machine with eight active sites working together.
Lomakin IB, Xiong Y, Steitz TA
Cell 2007 Apr 20 129(2):319-32 [abstract on PubMed] [related articles] [full text] [order article]
Selected by | Wolfgang Buckel
Evaluated 3 May 2007

Does Cob(II)alamin act as a conductor in coenzyme B12 dependent mutases?
Kozlowski PM, Kamachi T, Toraya T, Yoshizawa K
Angew Chem Int Ed Engl 2007 46(6):980-3 [abstract on PubMed] [related articles] [full text] [order article]
Selected by | Wolfgang Buckel
Evaluated 6 Mar 2007

Inactivation of E. coli pyruvate formate-lyase: role of AdhE and small molecules.
Nnyepi MR, Peng Y, Broderick JB
Arch Biochem Biophys 2007 Mar 1 459(1):1-9 [abstract on PubMed] [related articles] [full text] [order article]
Selected by | Wolfgang Buckel
Evaluated 23 Feb 2007

A novel oxalosuccinate-forming enzyme involved in the reductive carboxylation of 2-oxoglutarate in Hydrogenobacter thermophilus TK-6.
Aoshima M, Igarashi Y
Mol Microbiol 2006 Nov 62(3):748-59 [abstract on PubMed] [related articles] [full text] [order article]
Selected by | Wolfgang Buckel
Evaluated 23 Oct 2006

4-Hydroxyphenylacetate decarboxylases: properties of a novel subclass of glycyl radical enzyme systems.
Yu L, Blaser M, …, Pierik AJ, Selmer T
Biochemistry 2006 Aug 8 45(31):9584-92 [abstract on PubMed] [related articles] [full text] [order article]
Selected by | Wolfgang Buckel / E. Neil G. Marsh
Evaluated 21 Aug 2006

Molecular and functional analysis of nicotinate catabolism in Eubacterium barkeri.
Alhapel A, Darley DJ, …, Elsner N, Pierik AJ
Proc Natl Acad Sci U S A 2006 Aug 15 103(33):12341-6 [abstract on PubMed] [related articles] [FREE full text]
Selected by | Wolfgang Buckel
Evaluated 17 Aug 2006

Insights into phycoerythrobilin biosynthesis point toward metabolic channeling.
Dammeyer T, Frankenberg-Dinkel N
J Biol Chem 2006 Sep 15 281(37):27081-9 [abstract on PubMed] [related articles] [FREE full text]
Selected by | Wolfgang Buckel
Evaluated 4 Aug 2006

Large nonlinear effect observed in the enantiomeric excess of proline in solution and that in the solid state.
Hayashi Y, Matsuzawa M, …, Hashizume D, Koshino H
Angew Chem Int Ed Engl 2006 Jul 10 45(28):4593-7 [abstract on PubMed] [related articles] [full text] [order article]
Selected by | Wolfgang Buckel
Evaluated 20 Jul 2006

A nickel-alkyl bond in an inactivated state of the enzyme catalyzing methane formation.
Hinderberger D, Piskorski RP, …, Harmer J, Jaun B
Angew Chem Int Ed Engl 2006 May 26 45(22):3602-7 [abstract on PubMed] [related articles] [full text] [order article]
Selected by | Wolfgang Buckel
Evaluated 20 Jul 2006

Mössbauer and EPR study of recombinant acetyl-CoA synthase from Moorella thermoacetica.
Bramlett MR, Stubna A, …, Münck E, Lindahl PA
Biochemistry 2006 Jul 18 45(28):8674-85 [abstract on PubMed] [related articles] [full text] [order article]
Selected by | Wolfgang Buckel
Evaluated 20 Jul 2006

A new type of bacterial sulfatase reveals a novel maturation pathway in prokaryotes.
Berteau O, Guillot A, Benjdia A, Rabot S
J Biol Chem 2006 Aug 11 281(32):22464-70 [abstract on PubMed] [related articles] [FREE full text]
Selected by | Wolfgang Buckel / Judy Wall
Evaluated 22 Jun 2006

Deciphering the evolution and metabolism of an anammox bacterium from a community genome.
Strous M, Pelletier E, …, Wagner M, Le Paslier D
Nature 2006 Apr 6 440(7085):790-4 [abstract on PubMed] [related articles] [full text] [order article]
Selected by | Wolfgang Buckel / James Moir / Ian M. Head
Evaluated 20 Apr 2006

Evolution of enzymatic activities in the enolase superfamily: N-succinylamino acid racemase and a new pathway for the irreversible conversion of D- to L-amino acids.
Sakai A, Xiang DF, …, Raushel FM, Gerlt JA
Biochemistry 2006 Apr 11 45(14):4455-62 [abstract on PubMed] [related articles] [full text] [order article]
Selected by | Wolfgang Buckel / Reinhard Sterner
Evaluated 7 Apr 2006

Escherichia coli biotin synthase produces selenobiotin. Further evidence of the involvement of the [2Fe-2S]2+ cluster in the sulfur insertion step.
Tse Sum Bui B, Mattioli TA, …, Bolbach G, Marquet A
Biochemistry 2006 Mar 21 45(11):3824-34 [abstract on PubMed] [related articles] [full text] [order article]
Selected by | Wolfgang Buckel / Joan Broderick
Evaluated 14 Mar 2006

A radical solution for the biosynthesis of the H-cluster of hydrogenase.
Peters JW, Szilagyi RK, Naumov A, Douglas T
FEBS Lett 2006 Jan 23 580(2):363-7 [abstract on PubMed] [related articles] [full text] [order article]
Selected by | Wolfgang Buckel / Judy Wall
Evaluated 16 Jan 2006

An unprecedented twist to ODCase catalytic activity.
Fujihashi M, Bello AM, …, Pai EF, Kotra LP
J Am Chem Soc 2005 Nov 2 127(43):15048-50 [abstract on PubMed] [related articles] [full text] [order article]
Selected by | Wolfgang Buckel
Evaluated 8 Dec 2005

Biosynthesis of TDP-D-desosamine: identification of a strategy for C4 deoxygenation.
Szu PH, He X, Zhao L, Liu HW
Angew Chem Int Ed Engl 2005 Oct 21 44(41):6742-6 [abstract on PubMed] [related articles] [full text] [order article]
Selected by | Wolfgang Buckel
Evaluated 25 Oct 2005

Radical phosphate transfer mechanism for the thiamin diphosphate- and FAD-dependent pyruvate oxidase from Lactobacillus plantarum. Kinetic coupling of intercofactor electron transfer with phosphate transfer to acetyl-thiamin diphosphate via a transient FAD semiquinone/hydroxyethyl-ThDP radical pair.
Tittmann K, Wille G, …, Ghisla S, Hübner G
Biochemistry 2005 Oct 11 44(40):13291-303 [abstract on PubMed] [related articles] [full text] [order article]
Selected by | Wolfgang Buckel
Evaluated 21 Oct 2005

Methylcitrate synthase from Aspergillus fumigatus. Propionyl-CoA affects polyketide synthesis, growth and morphology of conidia.
Maerker C, Rohde M, Brakhage AA, Brock M
FEBS J 2005 Jul 272(14):3615-30 [abstract on PubMed] [related articles] [FREE full text]
Selected by | Wolfgang Buckel
Evaluated 26 Aug 2005

Zinc-proline catalyzed pathway for the formation of sugars.
Kofoed J, Machuqueiro M, Reymond JL, Darbre T
Chem Commun (Camb) 2004 Jul 7 (13):1540-1 [abstract on PubMed] [related articles] [full text]
Selected by | Wolfgang Buckel
Evaluated 18 May 2005

ATP-dependent enolization of acetone by acetone carboxylase from Rhodobacter capsulatus.
Boyd JM, Ensign SA
Biochemistry 2005 Jun 14 44(23):8543-53 [abstract on PubMed] [related articles] [full text] [order article]
Selected by | Wolfgang Buckel / Rowena Matthews
Evaluated 18 May 2005

Mechanistic investigations of lipoic acid biosynthesis in Escherichia coli: both sulfur atoms in lipoic acid are contributed by the same lipoyl synthase polypeptide.
Cicchillo RM, Booker SJ
J Am Chem Soc 2005 Mar 9 127(9):2860-1 [abstract on PubMed] [related articles] [full text] [order article]
Selected by | Marc Fontecave / Wolfgang Buckel
Evaluated 5 Apr 2005

The pyridine ring of NAD is formed by a nonenzymatic pericyclic reaction.
Colabroy KL, Begley TP
J Am Chem Soc 2005 Jan 26 127(3):840-1 [abstract on PubMed] [related articles] [full text] [order article]
Selected by | Wolfgang Buckel / Mark Nelson
Evaluated 18 Feb 2005

Isotope effects for deuterium transfer between substrate and coenzyme in adenosylcobalamin-dependent glutamate mutase.
Cheng MC, Marsh EN
Biochemistry 2005-02-22 44(7):2686-91 [abstract on PubMed] [related articles] [full text] [order article]
Selected by | Wolfgang Buckel
Evaluated 2 Feb 2005

Remarkable aliphatic hydroxylation by the diiron enzyme toluene 4-monooxygenase in reactions with radical or cation diagnostic probes norcarane, 1,1-dimethylcyclopropane, and 1,1-diethylcyclopropane.
Moe LA, Hu Z, …, Groves JT, Fox BG
Biochemistry 2004 Dec 21 43(50):15688-701 [abstract on PubMed] [related articles] [full text] [order article]
Selected by | Wolfgang Buckel
Evaluated 21 Dec 2004

Phenylphosphate carboxylase: a new C-C lyase involved in anaerobic phenol metabolism in Thauera aromatica.
Schühle K, Fuchs G
J Bacteriol 2004 Jul 186(14):4556-67 [abstract on PubMed] [related articles] [FREE full text]
Selected by | Wolfgang Buckel
Evaluated 24 Nov 2004

An organometallic intermediate during alkyne reduction by nitrogenase.
Lee HI, Igarashi RY, …, Seefeldt LC, Hoffman BM
J Am Chem Soc 2004 Aug 11 126(31):9563-9 [abstract on PubMed] [related articles] [FREE full text]
Selected by | Wolfgang Buckel / Mark Nelson
Evaluated 31 Aug 2004

Turning on ribonucleotide reductase by light-initiated amino acid radical generation.
Chang MC, Yee CS, Stubbe J, Nocera DG
Proc Natl Acad Sci U S A 2004 May 4 101(18):6882-7 [abstract on PubMed] [related articles] [FREE full text]
Selected by | Wolfgang Buckel
Evaluated 6 Aug 2004

An unusual mechanism of glycoside hydrolysis involving redox and elimination steps by a family 4 beta-glycosidase from Thermotoga maritima.
Yip VL, Varrot A, …, Anderson WF, Withers SG
J Am Chem Soc 2004 Jul 14 126(27):8354-5 [abstract on PubMed] [related articles] [full text] [order article]
Selected by | Wolfgang Buckel / Ben Davis / Mark Nelson / Sherry Mowbray
Evaluated 5 Aug 2004

Crystal structures of human glutaryl-CoA dehydrogenase with and without an alternate substrate: structural bases of dehydrogenation and decarboxylation reactions.
Fu Z, Wang M, …, Frerman FE, Kim JJ
Biochemistry 2004 Aug 3 43(30):9674-84 [abstract on PubMed] [related articles] [full text] [order article]
Selected by | Wolfgang Buckel
Evaluated 15 Jul 2004

Enzymatic characterization of a prokaryotic urea carboxylase.
Kanamori T, Kanou N, Atomi H, Imanaka T
J Bacteriol 2004 May 186(9):2532-9 [abstract on PubMed] [related articles] [FREE full text]
Selected by | Wolfgang Buckel
Evaluated 8 Jun 2004

Subunit composition of the glycyl radical enzyme p-hydroxyphenylacetate decarboxylase. A small subunit, HpdC, is essential for catalytic activity.
Andrei PI, Pierik AJ, …, Andrei-Selmer LC, Selmer T
Eur J Biochem 2004 Jun 271(11):2225-30 [abstract on PubMed] [related articles] [FREE full text]
Selected by | Wolfgang Buckel
Evaluated 28 May 2004

Direct determination of product radical structure reveals the radical rearrangement pathway in a coenzyme B12-dependent enzyme.
Warncke K, Canfield JM
J Am Chem Soc 2004 May 19 126(19):5930-1 [abstract on PubMed] [related articles] [full text] [order article]
Selected by | Wolfgang Buckel
Evaluated 25 May 2004

Blockage of methylcitrate cycle inhibits polyketide production in Aspergillus nidulans.
Zhang YQ, Keller NP
Mol Microbiol 2004 Apr 52(2):541-50 [abstract on PubMed] [related articles] [full text] [order article]
Selected by | Wolfgang Buckel
Evaluated 16 Apr 2004

Evolution of enzymatic activity in the enolase superfamily: structural and mutagenic studies of the mechanism of the reaction catalyzed by o-succinylbenzoate synthase from Escherichia coli.
Klenchin VA, Taylor Ringia EA, Gerlt JA, Rayment I
Biochemistry 2003 Dec 16 42(49):14427-33 [abstract on PubMed] [related articles] [full text] [order article]
Selected by | Wolfgang Buckel
Evaluated 5 Dec 2003

Transcarboxylase 12S crystal structure: hexamer assembly and substrate binding to a multienzyme core.
Hall PR, Wang YF, …, Carey PR, Yee VC
EMBO J 2003 May 15 22(10):2334-47 [abstract on PubMed] [related articles] [FREE full text]
Selected by | Wolfgang Buckel
Evaluated 6 Oct 2003

The first experimental test of the hypothesis that enzymes have evolved to enhance hydrogen tunneling.
Doll KM, Bender BR, Finke RG
J Am Chem Soc 2003 Sep 10 125(36):10877-84 [abstract on PubMed] [related articles] [full text] [order article]
Selected by | Joan Broderick / Arieh Warshel / Wolfgang Buckel
Evaluated 6 Oct 2003

The crystal structure of the Escherichia coli YfdW gene product reveals a new fold of two interlaced rings identifying a wide family of CoA transferases.
Gruez A, Roig-Zamboni V, …, Campanacci V, Cambillau C
J Biol Chem 2003 Sep 5 278(36):34582-6 [abstract on PubMed] [related articles] [FREE full text]
Selected by | Wolfgang Buckel
Evaluated 18 Jul 2003

Reversal of the apparent regiospecificity of NAD(P)H-dependent hydride transfer: the properties of the difluoromethylene group, a carbonyl mimic.
Leriche C, He X, Chang CW, Liu HW
J Am Chem Soc 2003 May 28 125(21):6348-9 [abstract on PubMed] [related articles] [full text] [order article]
Selected by | Wolfgang Buckel
Evaluated 16 Jun 2003

Crystal structure of the carboxyltransferase domain of acetyl-coenzyme A carboxylase.
Zhang H, Yang Z, Shen Y, Tong L
Science 2003 Mar 28 299(5615):2064-7 [abstract on PubMed] [related articles] [FREE full text]
Selected by | Wolfgang Buckel
Evaluated 9 Apr 2003

The pentacovalent phosphorus intermediate of a phosphoryl transfer reaction.
Lahiri SD, Zhang G, Dunaway-Mariano D, Allen KN
Science 2003 Mar 28 299(5615):2067-71 [abstract on PubMed] [related articles] [FREE full text]
Selected by | Wolfgang Buckel / Arieh Warshel / Alfred Wittinghofer / Janet Morrow
Evaluated 9 Apr 2003

3-Methylglutaconic aciduria type I is caused by mutations in AUH.
IJlst L, Loupatty FJ, …, Lehnert W, Wanders RJ
Am J Hum Genet 2002 Dec 71(6):1463-6 [abstract on PubMed] [related articles] [FREE full text]
Selected by | Wolfgang Buckel
Evaluated 15 Jan 2003

A Ni-Fe-Cu center in a bifunctional carbon monoxide dehydrogenase/acetyl-CoA synthase.
Doukov TI, Iverson TM, …, Ragsdale SW, Drennan CL
Science 2002 Oct 18 298(5593):567-72 [abstract on PubMed] [related articles] [FREE full text]
Selected by | Ruma Banerjee / Wolfgang Buckel / Joan Broderick
Evaluated 25 Oct 2002

Linearly concatenated cyclobutane lipids form a dense bacterial membrane.
Sinninghe Damsté JS, Strous M, …, van Niftrik LA, Jetten MS
Nature 2002 Oct 17 419(6908):708-12 [abstract on PubMed] [related articles] [full text] [order article]
Selected by | Wolfgang Buckel / Anna-Louise Reysenbach
Evaluated 25 Oct 2002

Biosynthesis of terpenes: studies on 1-hydroxy-2-methyl-2-(E)-butenyl 4-diphosphate reductase.
Adam P, Hecht S, …, Bacher A, Rohdich F
Proc Natl Acad Sci U S A 2002 Sep 17 99(19):12108-13 [abstract on PubMed] [related articles] [FREE full text]
Selected by | Wolfgang Buckel
Evaluated 12 Sep 2002

X-ray structure of pyruvate formate-lyase in complex with pyruvate and CoA. How the enzyme uses the Cys-418 thiyl radical for pyruvate cleavage.
Becker A, Kabsch W
J Biol Chem 2002 Oct 18 277(42):40036-42 [abstract on PubMed] [related articles] [FREE full text]
Selected by | Wolfgang Buckel
Evaluated 16 Aug 2002

The roles of coenzyme A in the pyruvate:ferredoxin oxidoreductase reaction mechanism: rate enhancement of electron transfer from a radical intermediate to an iron-sulfur cluster.
Furdui C, Ragsdale SW
Biochemistry 2002 Aug 6 41(31):9921-37 [abstract on PubMed] [related articles] [order article]
Selected by | Wolfgang Buckel
Evaluated 15 Aug 2002

Energetics and kinetics of lactate fermentation to acetate and propionate via methylmalonyl-CoA or acrylyl-CoA.
Seeliger S, Janssen PH, Schink B
FEMS Microbiol Lett 2002 May 21 211(1):65-70 [abstract on PubMed] [related articles] [order article]
Selected by | Wolfgang Buckel
Evaluated 20 Jun 2002

Functional expression of genes involved in the biosynthesis of the novel polyketide chain extension unit, methoxymalonyl-acyl carrier protein, and engineered biosynthesis of 2-desmethyl-2-methoxy-6-deoxyerythronolide B.
Kato Y, Bai L, …, Yu TW, Floss HG
J Am Chem Soc 2002 May 15 124(19):5268-9 [abstract on PubMed] [related articles] [order article]
Selected by | Wolfgang Buckel / Ben Shen
Evaluated 22 May 2002

The crystal structure of class II ribonucleotide reductase reveals how an allosterically regulated monomer mimics a dimer.
Sintchak MD, Arjara G, …, Stubbe J, Drennan CL
Nat Struct Biol 2002 Apr 9(4):293-300 [abstract on PubMed] [related articles] [full text] [order article]
Selected by | Amy Rosenzweig / Wolfgang Buckel / Mark Nelson
Evaluated 14 May 2002

A novel reaction between adenosylcobalamin and 2-methyleneglutarate catalyzed by glutamate mutase.
Huhta MS, Ciceri D, Golding BT, Marsh EN
Biochemistry 2002 Mar 5 41(9):3200-6 [abstract on PubMed] [related articles] [order article]
Selected by | Wolfgang Buckel
Evaluated 24 Apr 2002

Electron-nuclear double resonance spectroscopic evidence that S-adenosylmethionine binds in contact with the catalytically active [4Fe-4S](+) cluster of pyruvate formate-lyase activating enzyme.
Walsby CJ, Hong W, …, Broderick JB, Hoffman BM
J Am Chem Soc 2002 Mar 27 124(12):3143-51 [abstract on PubMed] [related articles] [order article]
Selected by | Wolfgang Buckel / Marc Fontecave / Mark Nelson
Evaluated 4 Apr 2002

Direct H atom abstraction from spore photoproduct C-6 initiates DNA repair in the reaction catalyzed by spore photoproduct lyase: evidence for a reversibly generated adenosyl radical intermediate.
Cheek J, Broderick JB
J Am Chem Soc 2002 Mar 27 124(12):2860-1 [abstract on PubMed] [related articles] [